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Reverse electrodialysis using Nafion™ membranes to produce renewable energy

In the order to address the global need for renewable and clean energy sources, salinity-gradient energy harvested by reverse electrodialysis (RED) is attracting significant interest in recent years. In addition, brine solution coming from seawater desalination is currently considered as a waste; however thanks to its high salinity it can be exploited as a valuable resource to feed RED. RED is an engineered adaptation of nature’s osmotic energy production where ions flow pass the cell membrane in order to produce the universal biological currency ATP. This energy is also harvested by the RED technology.

Now, more than ever there is need for sustainable and environmentally friendly technological solutions in order to keep up with ever growing demand for clean water and energy. The traditional linear way “produce and throw away” does no longer serve the society anymore and the new approach of circular economy has take a place, where any waste can be considered as a valuable resource for another process. In this respect, reverse electrodialysis is a promising electromembrane-based technology to generate power from concentrated solutions by harvesting the Gibbs free energy of mixing the solutions with different salinity. In particular, brine solutions produced in desalination plants, which is currently considered as a waste, can be used as concentrated streams in RED stack.

Avci et al. of the University of Calabria, Italy, have recently published their solution for brine disposal using RED-stack. They have realized that in order to maximize generated power, the high permselectivity and ion conductivity of membrane components in RED are essential. Although Nafion™ membranes are among the most prominent commercial cation exchange membrane solutions for electrochemical applications, no study has been done in its utilization toward RED processes. This was the first reported RED stack using Nafion™ membranes.

A typical RED unit is similar to an electrodialysis (ED) unit, which is a commercialized technology. ED uses a feed solution and the electrical energy, while producing concentrate and dilute, separately. On the other side, RED uses concentrated and dilute solutions that are mixed together in a controlled manner in order to produce spontaneously electrical energy. In a RED stack, repeating cells comprised of alternating cation and anion exchange membranes that are selective for anions and cations. The salinity gradient over each ion exchange membrane creates a voltage difference which is the driving force for the process. The ion exchange membranes are one of the most important components of a RED stack.

The performance of Nafion™ membranes (Nafion™ 117 and Nafion™ 115) have been evaluated under a high salinity gradient conditions for the possible application in RED. In order to simulate the natural environments of RED operation, NaCl solution as well as multicomponent NaCl + MgCl2 have been tested.

Gross power density under high salinity gradient and the effect of Mg2+ on the efficiency in energy conversion have been evaluated in single cell RED using Nafion™ 117, Nafion™ 115, CMX and Fuji-CEM-80050 as cation exchange membranes. Two commercial cation exchange membranes – CMX and Fuji-CEM 80050, frequently used for RED applications, have served as benchmark.

The results show that under the condition of 0.5 M / 4.0 M NaCl solutions, the highest Pd,max was achieved using Nafion™ membrane. This result is attributed to their outstanding permselectivity compared to other CEMs. In the presence of Mg2+ ions, Pd,max reduction of 17 and 20% for Nafion™ 115 and Nafion™ 117 were recorded, respectively. Both membranes maintained their low resistance; however a loss in permselectivity was measured under this condition. Even though, it was reported that Nafion™ membranes outperformed other commercial membranes such as CMX and Fuji-CEM-80050 for RED application.

(Photo: Wikipedia)